Directcontact Freezing Processes

Direct-contact processes have been investigated for large-scale seawater desalination applications (see Figure 7.37.10). Direct-contact processes use either a wash column or a vacuum-freezing, vapor-compression process.

The direct-contact freeze process uses direct contact with a refrigerant, such as butane, to effect crystallization. Therefore, the expensive scraped-surface units are unnecessary, and the process can produce larger crystals by using lower AT for crystallization.

The slurry containing the crystals moves to the wash column where the ice crystals rise due to their buoyancy, and countercurrent washing of the ice bed by fresh water takes place. The pure ice crystals are harvested off the top of the column and melted to produce demineralized water.

The vacuum-freezing, vapor-recompression process uses a hydroconverter and a washer (see Figure 7.37.11), and the feed solution enters the hydroconverter freezing chamber at the bottom. The refrigerant compressor causes vaporization in the vacuum chamber (3 to 5 mm Hg absolute), and the removal of the vaporization heat causes the formation of ice crystals in the water.

The slurry from the hydroconverter goes to the washer where the brine drains through the bottom while the crystals are returned to the hydroconverter at the top. They are melted by compressed vapors into pure demineralized water. The compressed vapors condense during this step and are drained with the melted ice as product effluent.

All direct-contact freezing processes require influent water pretreatment. The unavailability of large, axial, vapor compressors to handle the vapor volume at low pressures is the main limiting factor in the vacuum-freezing process.

0 0

Post a comment