Oxygen

FIG. 7.35.3 Three-stage oxygenation system that uses rotating spargers and recirculation compressors.

The Linde Division of Union Carbide (now independently operated as Praxair Inc.) demonstrated 95% oxygen utilization in the 1968 study of the Batavia, New York sewage works (Albertson et al., 1971; Gross 1976). (In 1980, the process named UNOX was acquired by Lotepro Corp., the U.S. subsidiary of Linde A.G. of Munich, Germany.) The Batavia plant covered its conventional aeration basins to prevent costly oxygen loss (see Figure 7.35.3). Efficient, upward-pumping, slow-speed, low-shear, agitator impellers kept the activated-sludge microbes in suspension. These agitators reduced energy needs for the 1-mgd plant to 4-5 hp, down from the previously estimated 35 hp for air sparging.

Table 7.35.1 shows test results of the UNOX process applied to industrial wastewater streams (Gross 1976). Oxygen is used in more than 250 wastewater treatment plants with an average capacity of 32 mgd.

The four following factors accelerate oxygen use:

1. Tighter legal water and air discharge limits. Tightening the legal discharge limits requires increased bacterial activity, better clarification, and lower excess sludge production. By maintaining optimum metabolic rates, pure oxygen cuts sludge production in half. With pure oxygen, odor problems are greatly reduced or eliminated.

2. New air separation technologies. Noncryogenic air-separation technologies, particularly membrane and pressure swing adsorption (PSA), make lower-cost oxygen available to customers that do not require the highest purity.

3. Better oxygen application techniques. These techniques are discussed later.

4. Wastewater treatment plant capacity shortages. Many plants are looking for effective ways to expand capacity or handle periodic overloads.

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