Soluble Organics Removal

The activated-sludge process, developed in England in the early 1900s, is remarkably successful at removing soluble organics from wastewater (Junkins, Deeny, and Eckhoff 1983; Tchobanoglous and Burton 1991; Vesilind and Pierce 1982). In an air-sparged tank (see Section 7.25), live microorganisms rapidly adsorb, then slowly oxidize these organics to carbon dioxide and water. At the same time, these organisms reproduce. The process removes the microorganism sludge by settling, while digestion of adsorbed organics continues, which activates the sludge for recycling.

Excess activated sludge is disposed after a dewatering attempt. Its disposal is the most difficult and costly aspect of this wastewater treatment. Even the best sludge dewa-tering equipment produces a sludge cake with not more than 14-18% dry solids.

Improvements are aimed at making the activated-sludge process more efficient. Advances in biotechnology and fluid dynamics allow stricter environmental standards to be attained. Three major advances are as follows:

1. The use of oxygen instead of air facilitates maintaining the required DO levels. It also makes sludge separation easier (see Figure 7.35.1). Therefore, an oxygen-sparged plant can operate at higher sludge levels with a smaller aeration tank, and sludge disposal is reduced.

2. Replacing the air or oxygen-sparged tank with a flu-idized-bed reactor allows the biomass to be adsorbed on small particles kept in suspension by the circulating effluent. This biofilm promotes high solids retention. The biomass concentration in the fluidized-bed reactor (15,000 ppm) is ten times greater than in the standard activated-sludge process. This increased concentration allows the fluid bed reactor to operate at a high, contaminant-removal efficiency.

3. Eliminating oxygen and using anaerobic methane fermentation of municipal wastewater in a fluidized-bed reactor is an even more efficient process. It is capable of operating with high biomass levels (30,000-100,000 ppm) at COD removal rates of 5-50 kg/m3/day.

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