The electrodialysis system in Figure 7.37.4 is inefficient for several reasons. As the ions migrate outward from the product chamber, the chamber progressively becomes depleted of ions, and its electrical resistance rises rapidly. This resistance determines the lower salinity limit in the product.
Increasing the operating temperature decreases resistance and thus improves the system performance. The build-up of solutes at the membrane-solid interface (concentration polarization) also increases electrical resistance. Ions in the feed water that precipitate due to a change in pH or are irreversibly adsorbed by the membranes can cause fouling. The back diffusion of salts due to an increase in salt concentration in one chamber can also reduce the separation efficiency. In addition, in all electro-dialysis systems, disposing the concentrated waste generated must be considered.
Was this article helpful?